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Merck - 8410770100 - Boron hydride-tetrahydrofuran complex

  • MFR SKU: 8410770100
  • ITEM #: 7167817
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Stock Status: SHIPS SOON (reserve your unit today)
Average lead time for this brand: 2-3 weeks. Specific products may vary.

ITEM #: 7167817
(stabilised) (1 molar solution in tetrahydrofuran) for synthesis
This listing is for 100 ml Glass bottle

Merck - 8410770100 - Boron hydride-tetrahydrofuran complex

  • Item #: 7167817
  • MFR SKU: 8410770100
Technical Specs
  • Catalogue Number 841077
  • HS Code 3824 99 92
  • Structure formula Image
  • Quality Level MQ200
  • Boiling point 66 ° C (1013 hPa) (THF)
  • Density 0.876 g/cm3 (25 ° C)
  • Explosion limit 1.58 - 12.42 %(V)
  • Flash point -21.7 ° C
  • Ignition temperature 103 ° C
  • LD 50 oral LD50 Rat > 500 - 2000 mg/kg
  • Hazard Pictogram(s)
  • Hazard Statement(s) H225: Highly flammable liquid and vapour.
  • H260: In contact with water releases flammable gases which may ignite spontaneously.
  • H302: Harmful if swallowed.
  • H318: Causes serious eye damage.
  • H335: May cause respiratory irritation.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.
  • EUH014: Reacts violently with water.
  • EUH019: May form explosive peroxides.
  • Precautionary Statement(s) P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P231 + P232: Handle and store contents under inert gas. Protect from moisture.
  • P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
  • P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
  • P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P308 + P313: IF exposed or concerned: Get medical advice/ attention.
  • P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
  • Signal Word Danger
  • Storage class 4.3 Hazardous materials, which set free flammable gases upon contact with water
  • WGK WGK 3 highly hazardous to water
  • Disposal 26
  • Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
  • Categories of danger highly flammable, irritant, carcinogenic, harmful
  • Storage Store at
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