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Sigma Aldrich / Merck - 12805-1G-F - (Benzotriazol-1-yloxy)tripyrrolidinophosphonium hexafluorophosphate

  • MFR SKU: 12805-1G-F
  • ITEM #: 16075733
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ITEM #: 16075733
Synonym: PyBOP (Benzotriazol-1-yloxy)tri pyrrolidinophosphonium hexafluorophosphate (PyBOP) is an activator of carboxyl group commonly used in peptide synthesis. It also participates in the carboxylic acid esterification. It shows characteristics similar to benzotriazol-1-yloxy)tris (dimethylamino)phosphoniu m hexafluorophosphate (BOP) and can be utilized as an alternative to BOP in peptide bond formation.
(Benzotriazol-1-yloxy)tri pyrrolidinophosphonium hexafluorophosphate (PyBOP) may be...
ITEM #: 16075733
Synonym: PyBOP (Benzotriazol-1-yloxy)tri pyrrolidinophosphonium hexafluorophosphate (PyBOP) is an activator of carboxyl group commonly used in peptide synthesis. It also participates in the carboxylic acid esterification. It shows characteristics similar to benzotriazol-1-yloxy)tris (dimethylamino)phosphoniu m hexafluorophosphate (BOP) and can be utilized as an alternative to BOP in peptide bond formation.
(Benzotriazol-1-yloxy)tri pyrrolidinophosphonium hexafluorophosphate (PyBOP) may be used in the following studies: • As coupling reagent in the preparation strategies for peptide-oligonucleotide conjugates. • Synthesis of structured pure triacylglycerol (TAG) regioisomers. • As coupling reagent in the synthesis of a 3, 5-pyrazolidinedione on soluble polyethylene glycol (PEG) polymer support. • Synthesis of herceptin- nanoparticles.
Analogue of the BOP coupling reagent which does not form carcinogenic HMPA as by-product.
PyBOP is a registered trademark of Merck KGaA, Darmstadt, Germany
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Sigma Aldrich / Merck - 12805-1G-F - (Benzotriazol-1-yloxy)tripyrrolidinophosphonium hexafluorophosphate

  • Item #: 16075733
  • MFR SKU: 12805-1G-F
Technical Specs
  • Quality Level :200
  • grade :purum
  • assay :≥ 97.0% (TLC)
  • application(s) :peptide synthesis: suitable
  • mp :~150 ° C
  • :154-156 ° C (dec.) (lit.)
  • storage temp. :2-8° C
  • SMILES string :F[P-](F)(F)(F)(F)F.C1CCN( C1)[P+](On2nnc3ccccc23)(N 4CCCC4)N5CCCC5
  • InChI :1S/ /c1-2-10 -18-17(9-1)19-20-24(18)25 -26(21-11-3-4-12-21, 22-13 -5-6-14-22)23-15-7-8-16-2 3; 1-7(2, 3, 4, 5)6/h1-2, 9-10 H, 3-8, 11-16H2;/q+1;-1
  • InChI key :VIAFLMPQBHAMLI-UHFFFAOYSA -N
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