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Sigma Aldrich / Merck - 232734-100ML - R-Alpine-Borane® solution

  • MFR SKU: 232734-100ML
  • ITEM #: 16089651
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ITEM #: 16089651
Synonym: B - Isopinocampheyl- 9- borabicyclo[3.3.1] nonane solution R -Alpine-Borane ® is a chiral reducing agent, synthesized from (+)-α-pinene via hydroboration.
R - and S -Alpine-Boranes are used for asymmetric reduction of aldehydes and prochiral ketones.
R -Alpine-Borane ® solution may be used to prepare: • ( R )-5-(Benzyloxy)pent-3-y-2 -ol, an intermediate for the stereoselective total synthesis of (-)-stagonolide D. • ( R )-1-( p -Tolyl)-1-pentyn-3-ol,...
ITEM #: 16089651
Synonym: B - Isopinocampheyl- 9- borabicyclo[3.3.1] nonane solution R -Alpine-Borane ® is a chiral reducing agent, synthesized from (+)-α-pinene via hydroboration.
R - and S -Alpine-Boranes are used for asymmetric reduction of aldehydes and prochiral ketones.
R -Alpine-Borane ® solution may be used to prepare: • ( R )-5-(Benzyloxy)pent-3-y-2 -ol, an intermediate for the stereoselective total synthesis of (-)-stagonolide D. • ( R )-1-( p -Tolyl)-1-pentyn-3-ol, an intermediate for the enatioselective synthesis of ( R )-incrustoporin. • N -( tert -Butyloxycarbonyl)-(4 S )-[4- 2 H]-1-L-homoserine tert -butyl ester, an intermediate for synthesizing (4 S )-[4- 2 H]-L-homoserine.
100 mL in Sure/Seal™
Alpine-Borane is a registered trademark of Sigma-Aldrich Co. LLC
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Sigma Aldrich / Merck - 232734-100ML - R-Alpine-Borane® solution

  • Item #: 16089651
  • MFR SKU: 232734-100ML
Technical Specs
  • Quality Level :100
  • optical activity :[α]20/D − 3.0°, neat
  • concentration :0.5  M in THF
  • density :0.896 g/mL at 25 ° C
  • SMILES string :C[C@H]1[C@@H](C[C@@H]2C[C @H]1C2(C)C)B3[C@@H]4CCC[C @H]3CCC4
  • InChI :1S/C18H31B/c1-12-16-10-13 (18(16, 2)3)11-17(12)19-14 -6-4-7-15(19)9-5-8-14/h12 -17H, 4-11H2, 1-3H3/t12-, 13 +, 14-, 15+, 16-, 17-/m1/s1
  • InChI key :VCDGSBJCRYTLNU-PHPOFCCKSA -N
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