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Sigma Aldrich / Merck - 317020-100G - (−)-DIP-Chloride™

  • MFR SKU: 317020-100G
  • ITEM #: 16091875
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ITEM #: 16091875
Synonym: (−)-B-Chlorodiisopinocampheylborane, (−)-Ipc 2 BCl 5, 25, 100 g in glass bottle
Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β -amino alcohols.
Reagent used for an enantioselective reduction of (chloroacetyl) benzofurans to chlorohydrins which serve as intermediates for the corresponding epoxides and aminoalcohols. For a short paper on the preparation of DIP halides and their use in stereoselective...
ITEM #: 16091875
Synonym: (−)-B-Chlorodiisopinocampheylborane, (−)-Ipc 2 BCl 5, 25, 100 g in glass bottle
Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β -amino alcohols.
Reagent used for an enantioselective reduction of (chloroacetyl) benzofurans to chlorohydrins which serve as intermediates for the corresponding epoxides and aminoalcohols. For a short paper on the preparation of DIP halides and their use in stereoselective reductions see Chem. Commun. 1053 (1994).
DIP-Chloride is a trademark of Sigma-Aldrich Co. LLC
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Sigma Aldrich / Merck - 317020-100G - (−)-DIP-Chloride™

  • Item #: 16091875
  • MFR SKU: 317020-100G
Technical Specs
  • Quality Level :100
  • mp :52-56 ° C (lit.)
  • SMILES string :C[C@H]1[C@@H](CC2CCC1C2(C )C)B(Cl)[C@@H]3CC4CCC([C@ H]3C)C4(C)C
  • InChI :1S/C20H34BCl/c1-11-15-7-1 3(19(15, 3)4)9-17(11)21(22 )18-10-14-8-16(12(18)2)20 (14, 5)6/h11-18H, 7-10H2, 1- 6H3/t11-, 12-, 13+, 14+, 15-, 16-, 17-, 18-/m1/s1
  • InChI key :PSEHHVRCDVOTID-VMAIWCPRSA -N
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