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Sigma Aldrich / Merck - D97754-1KG - Diethyl malonate

  • MFR SKU: D97754-1KG
  • ITEM #: 16104449
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ITEM #: 16104449
Synonym: Malonic acid diethyl ester Diethyl malonate is diethyl ester of malonic acid. Acylation of diethyl malonate using magnesium chloride and triethylamine is reported. K 2 CO 3 -catalyzed 1, 4-addition reaction of diethyl malonate with various substituted 1, 2-allenic ketones yields polyfunctionalized β, γ-unsaturated enones.
Diethyl malonate was used to investigate Knoevenagel condensation reactions in microreactor using zeolite catalysts obtained by grafting amino groups...
ITEM #: 16104449
Synonym: Malonic acid diethyl ester Diethyl malonate is diethyl ester of malonic acid. Acylation of diethyl malonate using magnesium chloride and triethylamine is reported. K 2 CO 3 -catalyzed 1, 4-addition reaction of diethyl malonate with various substituted 1, 2-allenic ketones yields polyfunctionalized β, γ-unsaturated enones.
Diethyl malonate was used to investigate Knoevenagel condensation reactions in microreactor using zeolite catalysts obtained by grafting amino groups onto NaX and CsNaX zeolites. It may be used in the synthesis of diethyl benzylidenemalonate by base catalyzed Knoevenagel condensation with benzaldehyde. It may be used in the synthesis of α-aryl malonates.
1, 2.5 kg in poly bottle
500 g in poly bottle
25 g in glass bottle
Packaged in glass bottles
ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC
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Sigma Aldrich / Merck - D97754-1KG - Diethyl malonate

  • Item #: 16104449
  • MFR SKU: D97754-1KG
  • Quality Level :200
  • vapor density :5.52 (vs air)
  • vapor pressure :1 mmHg ( 40 ° C)
  • product line :ReagentPlus ®
  • assay :99%
  • refractive index :n 20/D 1.413 (lit.)
  • bp :199 ° C (lit.)
  • mp :− 51-− 50 ° C (lit.)
  • density :1.055 g/mL at 25 ° C (lit.)
  • SMILES string :CCOC(=O)CC(=O)OCC
  • InChI :1S/C7H12O4/c1-3-10-6(8)5- 7(9)11-4-2/h3-5H2, 1-2H3
  • InChI key :IYXGSMUGOJNHAZ-UHFFFAOYSA -N

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